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UV curing

Role of Photoinitiators

Formulation Guidelines
 


UV curing
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Role of Photoinitiators

Formulation Guidelines

A single technology UltraViolet Curing is used to improve the quality of finished products while boosting productivity through substantial savings in energy,
time and labor.

In the UV curing process, ultraviolet light interacts with specially formulated chemistries to cure coatings faster and more economically than traditional methods. UV curing was developed more than 30 years ago especially for the printing, packaging, electronic and wood productsindustries.

Today, the UV curing industry is well positioned to shape coatings, ink and polymer technologies as we enter the 21st century. Initially a commercial success in the wood products and furniture indu-stries, UV curing is used today in a diverse number of industries. In the automotive industry, for example, these technologies are getting more and more common. Finished product manufacturers find that UV curing offers at least three outstanding benefits: environmental advantages, unique physical properties and production efficiencies.

Environmental Advantages

UV cured inks, coatings and adhesives have always contained very low levels of VOCs in the majority of cases zero VOC. These low-VOC-containing products become increasingly important, offering manufacturers a way to meet or exceed current and pending environmental regulations to limit emissions and control air quality.

Unique Physical Properties
UV curing is recognized as an “enhancement technology,” one that allows manufacturers to make their products more attractive and durable. Finished products exhibit exceptional stain, abrasion and solvent resistance coupled with superior toughness. Moreover, UV curing allows the printing and ink industries to achieve the highest gloss attainable by any coating method.

Production Efficiencies
UV curing offers manufacturers new production opportunities for a variety of specialty products, including optical fibers, photoimaging of printing plates and fast-curing wood fillers. In addition, new and specialized UV lamp systems allow for three-dimensional curing which opens markets for such new applications as bathroom vanities, molded plastic parts and furniture case goods. Most important, the UV curing process reduces drying times, improves production efficiency and provides pollution abatement. In addition, UV systems are typically easy to install on existing lines and, because items coming off the line are fully dry, UV technology can often lead to reductions in required factory space.

UV Curing Process
The UV curing process requires a light source which directs UV or visible light onto the formulated product. Photoinitiators absorb the UV energy from the light source, setting in motion a chemical reaction that quickly,
in fractions of a second, converts the liquid formulation into a solid, cured film. The bulk of the formulation is made up of monomers and oligomers. Monomers are low molecular weight materials.

They can be mono- or multifunctional molecules, depending on the number of reactive groups (usually acrylate) they possess. Functional monomers become part of the polymer matrix in the cured coating because their reactive functional groups undergo polymerization during exposure to
UV light. Monomers also function as diluents in the formulations, used
to adjust system viscosity, and are sometimes referred to as reactive diluents.

Oligomers, conversely, tend to be of higher molecular weight, viscous materials where the molecular weight ranges from several hundred to several thousand grams/ molecule or even higher. Usually, the type of oligomer backbone determines the final properties of the coating such
as flexibility, toughness, etc. These backbones can be epoxy, polyether, polyester, polyurethane or other types. The functional groups that provide linkage between molecules are located at both ends of the oligomer molecules. The functionality found to be most effective is the acrylate functional group.

A photoinitator can be categorized in different ways
According to its mechanism

  • free radical
  • cationic

According to its product form

  • liquid
  • solid

According to its absorption

  • UV light
  • visible light

According to its application

  • clear
  • pigmented
  • white

According to the depth of cure

  • thick layers
  • thin layers



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